Tuesday, December 30, 2014

The Problem with Fertilizer




Too much of a good thing is bad.  Just as too much food leads to obesity and tight pants, too much fertilizer contaminates the land and water we depend upon for food even while aiding the production of that food. The main environmental problem associated with fertilizer abuse is contamination of water with nitrates and phosphates, and the main problem with stories like this is that the technical explanation often goes in one ear and dribbles out the other. I’ll try to simplify the story here.

Only a fraction of nitrogen-based fertilizer is absorbed into plant matter. The rest accumulates in the soil where it is eventually converted by bacteria to nitrates, or is lost as run-off.  Nitrates are highly water-soluble, and leach into ground water or wash out of the soil into streams and rivers. High nitrate levels in drinking water are dangerous to human health. Because nitrogen is odorless and colorless, only testing can determine whether contamination has occurred. In January 2013, the California State Water Resources Control Board reported that more than 400 private wells and more than 200 water systems in the state were contaminated with nitrates.

When babies and the elderly drink water with high nitrogen levels, they can develop symptoms such as gastrointestinal swelling and irritation, diarrhea, and protein digestion problems—a condition called methemoglobinemia, or "blue baby syndrome." Infants whose skin tissues are low in oxygen appear to be blue or purplish in color. This occurs when nitrates mix with iron in red blood cells, leaving the blood unable to transport oxygen to the body's cells. Nitrates are dangerous enough; now let’s take a look at phosphates.

Although phosphorus itself is not washed out of soil, it combines with soil particles and travels with them to shallow water.  Phosphorus is not dangerous by itself, but in slow-moving water, it stimulates the growth of algae. Algae is not dangerous either – until it dies and decomposes removing oxygen from the water.  This kills fish and many other organisms. Scientists, never at a loss for unpronounceable obscure words, call this process eutrophication.

The lethal combination of excess nitrates and phosphates constitutes pollution that should be mitigated, but fertilizer is not the sole culprit. Other sources of these pollutants include industrial waste, sewage, detergents and manures. The problem of high nitrate levels in groundwater was actually recorded as early as 1860, long before synthetic fertilizer was invented.

A Little History…

In the 1910s and 1920s, Fritz Haber, a bespectacled German chemist, devised a way to manufacture ammonia from methane gas (NH3) and molecular nitrogen (N2). The ammonia from the Haber process, a process still used today, was then converted into nitric acid which led to the development of synthetic fertilizer—and significantly aided the German war effort. The synthetic supply of nitric acid was explosively useful in the manufacture of munitions.

Even more significantly than its destructive capabilities, The Haber process supported global population growth. It has been estimated that almost half the people on the planet are fed as a result of synthetic nitrogen fertilizer use. Ramped up to an industrial scale, ammonia synthesis has enabled widespread fertilization of croplands ever since. As a direct result, the world's population skyrocketed from 1.6 billion to six billion during the 20th century.

But Haber's nourishing discovery has a dark side. The surfeit of fertilizer has come at a high price for the environment.  And the story gets even better…

 Dead zone along coast of Maryland

Fertilizer’s Dark Side

Earth’s surging population demands ever increasing amounts of energy, and the burning of fossil fuels threatens the planet with catastrophic climate change as a warming blanket of greenhouse gases warms the oceans and melts arctic ice. In order to mitigate this problem, alternatives to fossil fuels are becoming more attractive. Biofuels perhaps?

Biofuels production in the US consists of ethanol manufactured from corn. Cornell University environmental biologist Robert Horwath who also chairs the International Scope Biofuels Project says, “The production of ethanol from corn in the US is a disaster in terms of fertilizer flowing down the Mississippi River.”  

He is undoubtedly concerned about the seasonal dead zone spreading from the Louisiana coast to Texas—covering approximately 5,000 square miles, an area roughly the size of Connecticut. The eutrophication in this dead zone is formed by nutrients that flush into the Gulf's waters -- largely agricultural fertilizer and wastewater from the Mississippi River. The resulting algae blooms suck up the oxygen in deep water, according to NOAA and the U.S. Geological Survey. Marine life struggles to find enough oxygen to survive within the zone.

As if this scenario weren’t scary enough already, fertilizers release significant quantities of nitrous oxide, a greenhouse gas with 300 times the heat-trapping capacity of carbon dioxide (CO2). Nobel laureate Paul Crutzen of the Max Planck Institute for Chemistry in Mainz, Germany, and his colleagues worry that cultivation of current biofuel crops, corn included, will wipe out any CO2 savings by releasing higher emissions of nitrous oxide and nitrogen oxide. The latter destroys the so-called “good” ozone, which shelters us from damaging ultraviolet radiation. It also contributes to ground level ozone, the main constituent in smog, widely known to exacerbate human respiratory ailments. According to the U.S. Environmental Protection Agency, millions of Americans live in areas that exceed the national standards for ozone exposure.

What Can We Do?

Despite the dangers posed by over-use of fertilizers, they enhance the growth of our food crops and beautify our landscapes—so they have value.  However, there are things we can do to alleviate the effects of fertilizer pollution, and small steps taken by many people can make a big difference.

  •        Before fertilizing, have your soil tested; then test every three years or so to determine the pH of your soil since crops require difference acidity levels.
  •          Follow package label instructions carefully and mix the fertilizer accurately.
  •          Do not allow excess water to run into streets or gutters, and leave a buffer zone when near a body of water.
  •          Apply fertilizer 4 to 6 inches into the soil using a coring device or a spike, and clean up all spilled fertilizer.  
  •          Because plant clippings contain phosphorus, debris should be removed and not directed into the street.
  •          Allow soil to replenish its nutrients naturally by giving it a break from crop production and by rotating crops.
  •          Avoid using fertilizer during the rain, and never apply it to frozen ground.
  •          Use organic fertilizers that consist of manures and animal wastes when practical.


 Further Reading
UNESCO has a web site worth exploring.   Scientific Committee on Problems of the Environment
Discover Buzzle at  http://www.buzzle.com/articles/how-do-fertilizers-affect-the-environment.html
Visit NOAA at  http://oceanservice.noaa.gov/education/kits/estuaries/media/supp_estuar09b_eutro.html

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